Startseite UB

Alpha-amino acid derivatives and alpha-fluoro ketones by enantioselective decarboxylation

URN to cite this document: urn:nbn:de:bvb:355-opus-2846

Baur, Markus A. (2003) Alpha-amino acid derivatives and alpha-fluoro ketones by enantioselective decarboxylation. PhD, Universität Regensburg

[img]
Preview
License: Publishing license for publications excluding print on demand
PDF
Download (775kB)

Abstract (German)

Die Methode der enantioselektiven Decarboxylierung wurde angewendet, um Enantiomeren-angereicherte alpha-Aminosäurederivate und alpha-Fluorketone zu erhalten. Als Substrate wurden 2-N-Acetylamino-2-alkylmalonsäuremonoethylester beziehungsweise beta-Keto-benzylester verwendet. China-Alkaloide und Derivate davon wurden als Katalysatoren eingesetzt. Die besten erhaltenen Ergebnisse waren ...

plus

Translation of the abstract (English)

The method of enantioselective decarboxylation was applied to obtain enantioenriched alpha-amino acid derivatives and alpha-fluoro ketones. 2-N-acetylamino-2-alkylmalonic monoethylesters respectively benzyl beta-ketoesters were applied as substrates. Cinchona alkaloids and derivatives of them were used as catalysts. The best results obtained were ethyl N-acetyl-L-phenylalaninate with 70% ...

plus


Export bibliographical data



Item Type:Thesis of the University of Regensburg (PhD)
Date:6 August 2003
Referee:Henri (Prof. Dr.) Brunner
Date of exam:15 July 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Henri Brunner
Keywords:Asymmetrische Synthese / Katalyse , Aminosäurederivate , Decarboxylierung , alpha-Fluorketone , China-Alkaloidderivate , Asymmetric catalysis , alpha-amino acid derivatives , alpha-fluoroketones , decarboxylation , cinchona alkaloid derivatives
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:26 Oct 2009 13:09
Last Modified:13 Mar 2014 11:17
Item ID:10117
Owner Only: item control page

Downloads

Downloads per month over past year

  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact