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The host/guest clathrate system [(ZnI2)6(ZnQ)]/[Pn4Qx] (Pn=P, As; Q=S, Se). A qualitative approach to structures, identification and synthesis

URN to cite this document: urn:nbn:de:bvb:355-opus-3450

Hong, Jung Hoon (2005) The host/guest clathrate system [(ZnI2)6(ZnQ)]/[Pn4Qx] (Pn=P, As; Q=S, Se). A qualitative approach to structures, identification and synthesis. PhD, Universität Regensburg

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Abstract (English)

The host/guest clathrate systems - [(ZnI2)6(ZnQ)]/[Pn4Qx] (Pn = P, As ; Q = S, Se) are obtained by one-step or two-step reaction of stoichiometric amounts of ZnI2, Pn, and Q or varying Q, I amounts in evacuated silica ampoules. The compounds consist of monomeric alpha-Pn4Q3 and alpha-Pn4Q4 cage molecules which are separated by a cubic host lattice of [(ZnI2)6(ZnQ)]. This contains almost spherical ...

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Translation of the abstract (German)

Die host/guest-Clathratsysteme [(ZnI2)6(ZnQ)]/[Pn4Qx] (Pn=P, As; Q=S, Se) werden erhalten aus ein- oder zweistufigen Reaktionen der stöchiometrischen Mengen von ZnI2, Pn und Q oder variablen Mengen an Q, I in evakuierten Quarzglasampullen. Die Verbindungen bestehen aus monomeren alpha-Pn4Q3 und alpha-Pn4Q4 Käfigmolekülen, die durch ein kubisches Gast-Gitter aus [(ZnI2)6(ZnQ)] ...

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Export bibliographical data

Item Type:Thesis of the University of Regensburg (PhD)
Date:9 January 2005
Referee:Prof. Dr. Arno Pfitzner
Date of exam:30 January 2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Keywords:Clathrate , Clathrate , Host , guest , phosphorus chalcogenide , zinc iodide
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:27 Oct 2009 06:48
Last Modified:13 Mar 2014 11:25
Item ID:10245
Owner Only: item control page
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