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Influence of Copper Salts, Solvents, and Ligands on the Structures of Precatalytic Phosphoramidite Copper Complexes for Conjugate Addition Reactions

Zhang, H. and Gschwind, R. M. (2007) Influence of Copper Salts, Solvents, and Ligands on the Structures of Precatalytic Phosphoramidite Copper Complexes for Conjugate Addition Reactions. Chemistry - A European Journal 13 (23), pp. 6691-6700.

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Abstract

For copper-catalyzed enantioselective conjugate addition reactions of organozinc reagents, the available knowledge about the mechanism and the structures involved is still insufficient to understand in detail the strong influences of solvent, salt, and ligand size, or to enable a rational control of this reaction. Screening with three phosphoramidite ligands and four copper(I) salts using NMR ...

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Item Type:Article
Date:2007
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/chem.200601857DOI
Keywords:asymmetric catalysis; conjugate addition; copper; NMR spectroscopy; phosphoramidite ligands
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Nikola Kastner-Pustet
Deposited On:11 Nov 2009 16:17
Last Modified:11 Nov 2009 16:17
Item ID:10627
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