Deutsch
Zhang, H. and Gschwind, R. M. (2006) Structure Identification of Precatalytic Phosphoramidite Complexes in Solution. Angewandte Chemie International Edition 45 (38), pp. 6391-6394.
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Abstract
1+1 is more than 2: A binuclear copper phosphoramidite precatalyst with mixed trigonal/tetrahedral coordination environments (see picture) is proposed based on NMR spectroscopy, mass spectrometry, and elemental analysis. The precatalyst represents a new structural motif for stereoselective copper catalysts and explains ligand acceleration and salt sensitivity in highly enantioselective 1,4-additions to enones.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Nikola Kastner-Pustet | ||||
| Deposited On: | 11 Nov 2009 17:12 | ||||
| Last Modified: | 11 Nov 2009 17:12 | ||||
| Item ID: | 10631 |
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