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Structure Identification of Precatalytic Phosphoramidite Complexes in Solution

Zhang, H. and Gschwind, R. M. (2006) Structure Identification of Precatalytic Phosphoramidite Complexes in Solution. Angewandte Chemie International Edition 45 (38), pp. 6391-6394.

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Abstract

1+1 is more than 2: A binuclear copper phosphoramidite precatalyst with mixed trigonal/tetrahedral coordination environments (see picture) is proposed based on NMR spectroscopy, mass spectrometry, and elemental analysis. The precatalyst represents a new structural motif for stereoselective copper catalysts and explains ligand acceleration and salt sensitivity in highly enantioselective ...

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Item Type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/anie.200601880DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Nikola Kastner-Pustet
Deposited On:11 Nov 2009 16:12
Last Modified:11 Nov 2009 16:12
Item ID:10631
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