Xie, X. and Auel, C. and Henze, W. and Gschwind, R. M. (2003) Dimethyl- and Bis[(trimethylsilyl)methyl]cuprates Show Aggregates higer than Dimers in Diethyl Ether: Molecular Diffusion Studies by PFG NMR and Aggregation-Reactivity Correlations. Journal of the American Chemical Society 125 (6), pp. 1595-1601.
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The molecular sizes of higher aggregates of dimethylcuprates (Me2CuLi (1), 1·LiI, and 1·LiCN) and bis[(trimethylsilyl)methyl]cuprates ((Me3SiCH2)2CuLi (2), 2·LiI, and 2·LiCN) in diethyl ether (Et2O) were determined by pulsed field gradient (PFG) NMR diffusion measurements. The obtained diffusion coefficients show molecular sizes larger than those of dimers for all systems. In these higher ...
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||No|
|Deposited On:||16 Nov 2009 10:42|
|Last Modified:||16 Nov 2009 10:42|