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The relation between ion pair structures and reactivities of lithium cuprates

John, M. and Auel, C. and Behrens, C. and Marsch, M. and Harms, K. and Bosold, F. and Gschwind, R. M. and Rajamohanan, P. R. and Boche, G. (2000) The relation between ion pair structures and reactivities of lithium cuprates. Chemistry - A European Journal 6 (16), pp. 3060-3068.

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Abstract

From Li+ well-solvating solvents or complex ligands such as THF, [12]crown-4, amines etc., lithium cuprates R2CuLi(.LiX) crystallise in a solvent-separated ion pair (SSIP) structural type (e.g. 10). In contrast, solvents with little donor qualities for Li+ such as diethyl ether or dimethyl sulfide lead to solid-state structures of the contact ion pair (CIP) type (e.g. 11). 1H,6Li HOESY NMR ...

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Item Type:Article
Date:2000
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/1521-3765(20000818)6:16<3060::AID-CHEM3060>3.0.CO;2-MDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Owner: Nikola Kastner-Pustet
Deposited On:11 Nov 2009 16:20
Last Modified:11 Nov 2009 16:20
Item ID:10651
Owner Only: item control page
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