Deutsch
Gandon, V. and Leboeuf, D. and Amslinger, S. and Vollhardt, K. P. C. and Malacria, M. and Aubert, C. (2005) Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-Diboryl-1,3-cyclohexadienes. Angew. Chem. Int. Ed. 44 (43), pp. 7114-7118.
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Abstract
Diborylated compounds are obtained by means of CpCo-mediated cocyclization of alkynyl(pinacol)boronic esters to alkenes followed by oxidative demetalation (see scheme). This strategy for the rapid and efficient construction of highly functionalized 1,3-cyclohexadienes and arenes is compatible with various substrates.
| Item Type: | Article | ||||||
|---|---|---|---|---|---|---|---|
| Additional information (public): | Times Cited: 0 | ||||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Sabine Amslinger | ||||||
| Identification Number: |
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| Keywords: | alkenes alkynylboronates cobalt cycloaddition diene ligands | ||||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||||
| Status: | Published | ||||||
| Refereed: | Yes, this version has been refereed | ||||||
| Created at the University of Regensburg: | No | ||||||
| Owner: | Dr. Sabine Amslinger | ||||||
| Deposited On: | 24 Nov 2009 15:59 | ||||||
| Last Modified: | 07 Nov 2012 11:17 | ||||||
| Item ID: | 11067 |
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