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Photochemistry of Azide Complexes of Gold, Silver, Platinum and Palladium. Generation of the Metallic State

Vogler, Arnd and Quett, C. and Kunkely, Horst (1988) Photochemistry of Azide Complexes of Gold, Silver, Platinum and Palladium. Generation of the Metallic State. Berichte der Bunsen-Gesellschaft für Physikalische Chemie 92, pp. 1486-1492.

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Abstract

The photochemistry of the following azide complexes in organic solvents has been investigated: [Au(N3)4]⁻, [Au(N3)2]⁻, [Ag(PPh3)2N3], [Pt(N3)6]2⁻, [Pt(N3)4]2⁻, [Pd(N3)4]2⁻, and [Pd2(N3)6]2⁻. All complexes underwent a photochemical reduction of the metal and oxidation of azide upon ligand to metal charge transfer excitation. The photolysis of the complexes with the metals in the lower oxidation ...

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Item Type:Article
Date:1988
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Keywords:Colloides I Complex Compounds / Metals / Photochemistry / Spectroscopy, Ultraviolet
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:15 Mar 2010 06:23
Last Modified:13 Mar 2014 13:03
Item ID:13339
Owner Only: item control page

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