Vogler, Arnd and Kunkely, Horst (1988) Photochemistry of [MCo₂(CO)₈] (M=Zn, Cd, Hg) induced by metal to metal charge transfer excitation. Journal of Organometallic Chemistry 355 (1-3), pp. 1-6.
The electronic absorption spectra of the complexes [(OC),Co-‘M”Co-‘(CO),] with M = Zn, Cd, and Hg display an intense long-wavelength band which is assigned to the allowed Σu+ -> Σg+ transition from a non-bonding σ to an antibonding σ orbital of the Co-M-Co moiety. This transition is shifted to higher energies and gains an increasing charge transfer (CT) contribution in changing M in the ...
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||15 Mar 2010 06:22|
|Last Modified:||13 Mar 2014 13:03|