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Photochemistry of [MCo₂(CO)₈] (M=Zn, Cd, Hg) induced by metal to metal charge transfer excitation

Vogler, Arnd and Kunkely, Horst (1988) Photochemistry of [MCo₂(CO)₈] (M=Zn, Cd, Hg) induced by metal to metal charge transfer excitation. Journal of Organometallic Chemistry 355 (1-3), pp. 1-6.

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Abstract

The electronic absorption spectra of the complexes [(OC),Co-‘M”Co-‘(CO),] with M = Zn, Cd, and Hg display an intense long-wavelength band which is assigned to the allowed Σu+ -> Σg+ transition from a non-bonding σ to an antibonding σ orbital of the Co-M-Co moiety. This transition is shifted to higher energies and gains an increasing charge transfer (CT) contribution in changing M in the ...

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Item Type:Article
Date:1988
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0022-328X(88)89005-3DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:15 Mar 2010 06:22
Last Modified:13 Mar 2014 13:03
Item ID:13340
Owner Only: item control page

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