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Photoredox Reaction of Cobalticinium Pentacarbonylmanganate(-I) induced by Outer-Sphere Metal to Metal Charge Transfer Excitation

Kunkely, Horst and Vogler, Arnd (1989) Photoredox Reaction of Cobalticinium Pentacarbonylmanganate(-I) induced by Outer-Sphere Metal to Metal Charge Transfer Excitation. Journal of Organometallic Chemistry 372 (3), C29-C32.

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Abstract

The salts [Co(C5H5)2]+ wavelength absorptions at [Mn(CO)5]- and [Cr(C6H6)2]+ [Mn(CO)5]- show longwavelength absorptions at λmax 740 nm and 665 nm. These bands assigned to metal to metal charge transfer (MMCT) transitions from Mn-I to CoIII and CrI. Upon MMCT excitation the former ion pair is converted to Co(C5H5)2 and Mn 2(CO)10. The latter ion pair undergoes an analogous redox reaction as a ...

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Item Type:Article
Date:1989
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0022-328X(89)87240-7DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:15 Mar 2010 06:32
Last Modified:13 Mar 2014 13:03
Item ID:13343
Owner Only: item control page

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