Deutsch
Kunkely, Horst and Vogler, Arnd (1989) Photoredox Reaction of [Cr(CO)₅I] induced by Ligand to Metal Charge Transfer Excitation. Journal of Organometallic Chemistry 378 (2), C15-C17.
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Abstract
The complex [CrI(CO)5I] is characterized by a long-wavelength absorption at λmax 638 nm. This band is assigned to a ligand to metal charge transfer (LMCT) transition from iodide (π) to CrI (t2g). Upon LMCT excitation the complex undergoes a photoredox reaction with a quantum yield φ 0.01 according to the equation: [CrI(CO)5I] + CH3CN → [Cr0(CO)5CH3CN] + I/2 I2. This reaction takes place also thermally.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Universitätsbibliothek Regensburg | ||||
| Deposited On: | 15 Mar 2010 07:21 | ||||
| Last Modified: | 21 Jul 2011 00:22 | ||||
| Item ID: | 13344 |
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