Kunkely, Horst and Vogler, Arnd (1989) Photoredox Reaction of [Cr(CO)₅I] induced by Ligand to Metal Charge Transfer Excitation. Journal of Organometallic Chemistry 378 (2), C15-C17.
The complex [CrI(CO)5I] is characterized by a long-wavelength absorption at λmax 638 nm. This band is assigned to a ligand to metal charge transfer (LMCT) transition from iodide (π) to CrI (t2g). Upon LMCT excitation the complex undergoes a photoredox reaction with a quantum yield φ 0.01 according to the equation: [CrI(CO)5I] + CH3CN → [Cr0(CO)5CH3CN] + I/2 I2. This reaction takes place also thermally.
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||15 Mar 2010 06:21|
|Last Modified:||13 Mar 2014 13:03|