Go to content
UR Home

Optical ligand-to-ligand charge transfer of Zn(2,2'-bipyridyl)(3,4-toluenedithiolate)

Benedix, R. and Hennig, H. and Kunkely, Horst and Vogler, Arnd (1990) Optical ligand-to-ligand charge transfer of Zn(2,2'-bipyridyl)(3,4-toluenedithiolate). Chemical Physics Letters 175, pp. 483-487.

[img]
Preview
PDF
Download (363kB)

at publisher (via DOI)


Abstract

The electronic structure and the optical ligand-to-ligand charge transfer (LLCT) of the pseudotetrahedral complex Zn (2,2′-bipyridyl) (3,4-toluenedithiolate) is interpreted on the basis of EHT calculations. By comparison with square-planar complexes, it is shown that the extent of electron delocalization between donor and acceptor ligand and charge separation by LLCT excitation depends on the mutual orientation of both ligands.


Export bibliographical data



Item Type:Article
Date:1990
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0009-2614(90)85568-WDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:15 Mar 2010 06:31
Last Modified:13 Mar 2014 13:03
Item ID:13346
Owner Only: item control page

Downloads

Downloads per month over past year

  1. Homepage UR

University Library

Publication Server

Contact person
Gernot Deinzer

Phone +49 941 943-2759
Contact