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Photoredox Chemistry of Chloro Complexes of Antimony(III) and (V)

Vogler, Arnd and Paukner, A. (1989) Photoredox Chemistry of Chloro Complexes of Antimony(III) and (V). Inorganica Chimica Acta 163 (2), pp. 207-211.

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Abstract

The complex [SbCl6]3− in CHCl3 shows a phosphorescence (λmax = 520 nm, ø = 2.4 X 10−3, τ 50 ns) originating from the lowest sp excited state. Oxygen quenches this luminescence and participates in the photooxidation of Sb(III): [SbCl6]3− + O2 → [SbCl6]− + O22−. At λirr = 263 nm the quantum yield was ø = 0.081. The photoproduct [SbCl6]− in CHCl3 is light-sensitive too. Ligand to metal charge ...

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Item Type:Article
Date:1989
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/S0020-1693(00)83453-2DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:16 Mar 2010 05:57
Last Modified:13 Mar 2014 13:03
Item ID:13359
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