Türk, T. and Resch, U. and Fox, M.A. and Vogler, Arnd
Cadmium Benzenethiolate Clusters of Various Size: Molecular Models for Metal Chalcogenide Semiconductors.
The Journal of Physical Chemistry 96 (9), pp. 3818-3822.
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The optical and electrochemical properties of three cadmium benzenethiolate clusters, Cd(SPh)4 2-, Cd4(SPh)10 2-, and
Cd10 $4(SPh)16 4-, are studied as function of the cluster size. The Cdn clusters (n = 1,4, 10) which may represent molecular models for the semiconductor CdS show structured absorption spectra that are assigned to both ligand-to-metal charge-transfer (LMCT) and intraligand ...
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