Deutsch
Kunkely, Horst and Vogler, Arnd (1989) Photoredox Reaction of Triazidomercurate(II). Generation of Stable Mercury Atoms under Ambient Conditions. Polyhedron 8 (22), pp. 2731-2733.
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Abstract
Upon ligand-to-metal charge-transfer excitation the complex [Hg(N3)3]− in ethanol underwent a photoredox reaction (λirr = 254 nm; Ø = 0.02): [HgII(N3)3]− → Hg0+ 3N2 + N3−. Elemental mercury was released in the form of metal atoms which are stable under ambient conditions.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Universitätsbibliothek Regensburg | ||||
| Deposited On: | 16 Mar 2010 06:58 | ||||
| Last Modified: | 15 Dec 2011 13:58 | ||||
| Item ID: | 13375 |
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