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Photoredox Reaction of Triazidomercurate(II). Generation of Stable Mercury Atoms under Ambient Conditions

Kunkely, Horst and Vogler, Arnd (1989) Photoredox Reaction of Triazidomercurate(II). Generation of Stable Mercury Atoms under Ambient Conditions. Polyhedron 8 (22), pp. 2731-2733.

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Abstract

Upon ligand-to-metal charge-transfer excitation the complex [Hg(N3)3]− in ethanol underwent a photoredox reaction (λirr = 254 nm; Ø = 0.02): [HgII(N3)3]− → Hg0+ 3N2 + N3−. Elemental mercury was released in the form of metal atoms which are stable under ambient conditions.


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Item Type:Article
Date:1989
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/S0277-5387(00)80448-9DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:16 Mar 2010 05:58
Last Modified:13 Mar 2014 13:04
Item ID:13375
Owner Only: item control page

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