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Optical Metal to Ligand Charge Transfer of 2,2'-Bipyridyl Complexes of Antimony(III) and Bismuth(III)

Kunkely, Horst and Paukner, A. and Vogler, Arnd (1989) Optical Metal to Ligand Charge Transfer of 2,2'-Bipyridyl Complexes of Antimony(III) and Bismuth(III). Polyhedron 8 (24), pp. 2937-2939.

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Abstract

The complexes [M(2,2′-bipyridyl)X3], with M = Sb, Bi and X = Cl, Br, I, are characterized by long-wavelength metal-to-ligand charge-transfer (MLCT) bands which determine the colours of these compounds in the solid state. The energy of the MLCT bands depends on the reducing strength of the metal and the extent of sp mixing of the lone electron pair at the ...

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Item Type:Article
Date:1989
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/S0277-5387(00)86294-4DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:16 Mar 2010 05:58
Last Modified:13 Mar 2014 13:04
Item ID:13376
Owner Only: item control page

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