Kunkely, Horst and Paukner, A. and Vogler, Arnd (1989) Optical Metal to Ligand Charge Transfer of 2,2'-Bipyridyl Complexes of Antimony(III) and Bismuth(III). Polyhedron 8 (24), pp. 2937-2939.
The complexes [M(2,2′-bipyridyl)X3], with M = Sb, Bi and X = Cl, Br, I, are characterized by long-wavelength metal-to-ligand charge-transfer (MLCT) bands which determine the colours of these compounds in the solid state. The energy of the MLCT bands depends on the reducing strength of the metal and the extent of sp mixing of the lone electron pair at the metal.
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||16 Mar 2010 05:58|
|Last Modified:||13 Mar 2014 13:04|