Vogler, Arnd and Kunkely, Horst
Optical Ligand to Ligand Charge Transfer of Metal Complexes Including Ligand-Based Mixed-Valence Systems.
Comments on Inorganic Chemistry 9 (3), pp. 201-220.
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The electronic spectra of metal complexes which contain a reducing and an oxidizing ligand (Lred-M-Lox) are characterized by ligand to ligand charge transfer (LLCT) absorptions. A specific form of Lred-M-Lox complexes are ligand-based mixed-valence (LBMV) compounds which contain the same ligand in two different redox states. In this case the ligand-ligand interaction may lead to a partial or even ...
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