Vogler, Arnd and Kunkely, Horst
Photochemistry of Transition Metal Complexes Induced by Outer-Sphere Charge Transfer Excitation.
Photoinduced Electron Transfer II.
Topics in Current Chemistry, 158.
Springer, Berlin, pp. 1-30.
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The intermolecular (outer sphere, OS) interaction of a reducing and an oxidizing metal complex generates a new optical transition involving charge transfer (CT) from the electron donor to the acceptor. OS CT transitions are classified according to the redox site (metal or ligand). Generally, the interaction between donor and acceptor is facilitated by ion pairs consisting of an oxidizing complex ...
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