Sabin, F. and Vogler, Arnd
Luminescence of Dimeric T1(I) Complexes: Metal-Metal Interaction in the Electronically Excited State.
Monatshefte für Chemie / Chemical Monthly 123 (8-9), pp. 705-708.
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Dimeric diethyldithiocarbamatethallium(I) [Et 2NCS2Tl]2 shows a red emission at λmax=608 nm which undergoes a huge Stokes shift with regard to the excitation maximum at λ=246 nm. It is suggested that the emission originates from a sp excited state which is characterized by strong metal-metal ...
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