Luminescence of Dimeric T1(I) Complexes: Metal-Metal Interaction in the Electronically Excited State

Sabin, F. and Vogler, Arnd (1992) Luminescence of Dimeric T1(I) Complexes: Metal-Metal Interaction in the Electronically Excited State. Monatshefte für Chemie / Chemical Monthly 123 (8-9), pp. 705-708.

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Abstract

Dimeric diethyldithiocarbamatethallium(I) [Et 2NCS2Tl]2 shows a red emission at λmax=608 nm which undergoes a huge Stokes shift with regard to the excitation maximum at λ=246 nm. It is suggested that the emission originates from a sp excited state which is characterized by strong metal-metal bonding.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1007/BF00812319DOI
Keywords:Dialkyldithiocarbamatethallium(I) - Luminescence - Metal-metal interaction
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner:Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 07:12
Last Modified:21 Jul 2011 00:23
Item ID:13509
Owner Only: item control page