Kunkely, Horst and Vogler, Arnd (1992) Photooxidation of AuCl₂⁻ and AuBr₂⁻ Induced by ds Excitation. Inorganic Chemistry 31 (22), pp. 4539-4541.
In the presence of electron acceptors such as CHzC12 or 02, the irradiation of AuC12- or AuBrz- in acetonitrile led
to the photooxidation of Au(1) to Au(II1). AuC14- and AuBr4- were formed as final products when additional halide
was present. The reactive excited states were of the metal-centered ds type. The photooxidations were reversed
in solutions of ethanol. AuC14- and AuBr4- underwent a photoreduction to AuC12- and AuBrz-, respectively.
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||17 Mar 2010 06:26|
|Last Modified:||13 Mar 2014 13:05|