Horváth, O. and Vogler, Arnd
Photoredox Chemistry of Chloromercurate(II) Complexes in Acetonitrile.
Inorganic Chemistry 32, pp. 5485-5489.
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The kinetically labile chloromercurates(II) have rather high stepwise formation constants in acetonitrile; even for
HgCI42- a value of 1.07 X lo4 M-I was determined. The ultraviolet spectra of these complexes are characterized
by ligand-to-metal charge-transfer transitions of different energies and intensities. Their photolysis leads to the
formation of Hg(I) and Cl in the primary ...
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