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Photoredox Chemistry of Chloromercurate(II) Complexes in Acetonitrile

Horváth, O. and Vogler, Arnd (1993) Photoredox Chemistry of Chloromercurate(II) Complexes in Acetonitrile. Inorganic Chemistry 32, pp. 5485-5489.

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Abstract

The kinetically labile chloromercurates(II) have rather high stepwise formation constants in acetonitrile; even for HgCI42- a value of 1.07 X lo4 M-I was determined. The ultraviolet spectra of these complexes are characterized by ligand-to-metal charge-transfer transitions of different energies and intensities. Their photolysis leads to the formation of Hg(I) and Cl in the primary ...

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Item Type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1021/ic00076a014DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 06:25
Last Modified:13 Mar 2014 13:05
Item ID:13515
Owner Only: item control page
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