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Photoredox Reactions of Lead(IV) and -(II) Hydroxo Complexes

Becht, A. and Vogler, Arnd (1993) Photoredox Reactions of Lead(IV) and -(II) Hydroxo Complexes. Inorganic Chemistry 32 (13), pp. 2835-2837.

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Abstract

Ligand-to-metal charge-transfer excitation of Pb(OH)62- in 0.1 M NaOH leads to the formation of Pb(0H)3- with φ = 0.07 at λirr = 254 nm. Hydrogen peroxide was detected as an oxidation product. Upon sp excitation, Pb(OH)3- in 0.1 M NaOH shows a yellow emission at λmax = 570 nm with φ = 1.5 X 10-3 at λirr = 254 nm. In the presence of oxygen, this emission is partially quenched (φ = 1.2 X 10-3) ...

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Item Type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1021/ic00065a009DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 06:23
Last Modified:13 Mar 2014 13:05
Item ID:13523
Owner Only: item control page

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