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Photochemistry of cyclopentadienylthallium(I)

Kunkely, Horst and Vogler, Arnd (1993) Photochemistry of cyclopentadienylthallium(I). Journal of Organometallic Chemistry 459 (1-2), pp. 21-23.

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Abstract

TlC5H5 displays absorption maxima at 228 and 280 nm which are assigned to metal-centred sp and ligand-to-metal charge transfer (LMCT) transitions, respectively. The complex shows an emission at λmax = 360 nm which originates from a low-energy sp excited state. The photolysis of TlC5H5 in methanol proceeds according to the equation TlC5H5 + CH3OH → TlOH + H2 + C6H6 (pentafulvene) with φ = 0.1 at ...

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Item Type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0022-328X(93)86052-JDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 06:22
Last Modified:13 Mar 2014 13:05
Item ID:13532
Owner Only: item control page

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