Benedix, R. and Vogler, Arnd (1993) Electronic Structure and Spectroscopic Properties of Copper Catecholate Complexes with Interligand Charge Transfer Behavior. Inorganica Chimica Acta 204 (2), pp. 189-193.
The structural and spectroscopic properties of copper catecholate complexes with nitrogen ligands of the α- diimine type are studied by qualitative MO considerations. The characteristic feature of these donor acceptor systems is an interligand charge-transfer from the catecholate donor to the α-diimine acceptor site. The dependence of the interligand charge-transfer absorption band on the energies of the acceptor and the donor levels as well as on the solvent polarity is discussed.
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||17 Mar 2010 09:03|
|Last Modified:||13 Mar 2014 13:06|