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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-135647
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.13564
Zusammenfassung
The structural and spectroscopic properties of copper catecholate complexes with nitrogen ligands of the α- diimine type are studied by qualitative MO considerations. The characteristic feature of these donor acceptor systems is an interligand charge-transfer from the catecholate donor to the α-diimine acceptor site. The dependence of the interligand charge-transfer absorption band on the energies of the acceptor and the donor levels as well as on the solvent polarity is discussed.