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Photoredox behavior of a trinuclear Ru(III), Ru(II), Co(III) complex induced by metal-to-metal charge transfer excitations

Kunkely, Horst and Pawlowski, V. and Vogler, Arnd (1994) Photoredox behavior of a trinuclear Ru(III), Ru(II), Co(III) complex induced by metal-to-metal charge transfer excitations. Inorganica Chimica Acta 225 (1-2), pp. 327-330.

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Abstract

The trinuclear complex (NH3)5CoIII(μ-NC)CoIII(CN)4(μ-CN)RuII(CN)53− shows a long wavelength absorption near 370 nm which is assigned to a metal-to-metal charge transfer (MMCT) transition from Ru(II) to the central Co(III) ion. Light absorption by this bands leads to a redox decomposition: (NH3)5CoIII(CN)4(μ-CN)RuII(CN)53−→5NH3+ Co2++CoIII(CN)63−+ RuIII(CN)5H2O2−. It is suggested that the initial ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0020-1693(94)04021-4DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 09:02
Last Modified:13 Mar 2014 13:06
Item ID:13566
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