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Photoredox chemistry of iodomercurate(II) complexes in acetonitrile

Horváth, O. and Vogler, Arnd (1994) Photoredox chemistry of iodomercurate(II) complexes in acetonitrile. Inorganica Chimica Acta 221 (1-2), pp. 79-84.

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Abstract

The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/0020-1693(94)03950-XDOI
Keywords:Photochemistry; Redox reactions; Mercury complexes; Iodo complexes
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 09:11
Last Modified:13 Mar 2014 13:06
Item ID:13567
Owner Only: item control page

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