Horváth, O. and Vogler, Arnd (1994) Photoredox chemistry of iodomercurate(II) complexes in acetonitrile. Inorganica Chimica Acta 221 (1-2), pp. 79-84.
The stepwise formation constants of the kinetically labile iodomercurates(II) in acetonitrile are relatively high; even for the tetraiodo complex a value of 1220 was determined. Ligand-to-metal charge transfer transitions of different energies and intensities feature the ultraviolet spectra of these compounds. Photolysis of their CH3CN solution results in the formation of Hg(l) and I or I2− as ...
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Keywords:||Photochemistry; Redox reactions; Mercury complexes; Iodo complexes|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||17 Mar 2010 09:11|
|Last Modified:||13 Mar 2014 13:06|