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Photoredox Reaction of [Hg(cyclam)]²⁺[Co(CO)₄]⁻ Induced by Outer Sphere Charge Transfer Excitation

Kunkely, Horst and Vogler, Arnd (1993) Photoredox Reaction of [Hg(cyclam)]²⁺[Co(CO)₄]⁻ Induced by Outer Sphere Charge Transfer Excitation. Zeitschrift für Naturforschung B 48, pp. 397-398.

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The ion pair [Hg(cyclam)]2+[Co(CO)4]- displays
a Co(-I) to Hg(II) metal-to-metal charge
transfer (MMCT) band at 288 nm. Upon MMCT
excitation the ion pair undergoes a photoconversion
to [HgC02(CO)8].

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Keywords:Photoredox Reaction, Charge Transfer, Mercury(II), Cobalt(-I)
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited on:17 Mar 2010 09:06
Last modified:13 Mar 2014 13:06
Item ID:13572
Owner only: item control page


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