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Photophysics and photochemistry of main group metals with an s² electron configuration. Luminescence quenching and photoreduction of trihydroxoplumbate(II) by hydroxide

Becht, A. and Vogler, Arnd (1994) Photophysics and photochemistry of main group metals with an s² electron configuration. Luminescence quenching and photoreduction of trihydroxoplumbate(II) by hydroxide. Journal of Chemical Sciences 106 (3), pp. 639-643.

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Abstract

The luminescence of Pb(OH) 3 − in deaerated aqueous solution is quenched by hydroxide withk = 1.87 × 105 Lmol−1 s−1. It is suggested that this quenching is associated with an electron transfer from hydroxide to Pb(OH) 3 − in its3P1 sp-excited state. This assumption is supported by the photochemical behaviour of Pb(OH) 3 − which is photoreduced to metallic lead. The efficiency of the photolysis ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1007/BF02911094DOI
Keywords:Photochemistry - luminescence - lead (II) - hydroxo complex
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 09:37
Last Modified:13 Mar 2014 13:08
Item ID:13590
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