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Photochemistry and Photophysics of Antimony(III) Hyper Porphyrins: Activation of Dioxygen Induced by a Reactive sp Excited State

Knör, Günther and Vogler, Arnd (1994) Photochemistry and Photophysics of Antimony(III) Hyper Porphyrins: Activation of Dioxygen Induced by a Reactive sp Excited State. Inorganic Chemistry 33 (2), pp. 314-318.

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Abstract

Observations of the photoredox reactivity of antimony(III) porphyrin complexes are reported. Upon irradiation with visible light under ambient conditions, a photooxidation to the corresponding dihydroxoantimony(V) porphyrins occurs. At the same time a two-electron or four-electron reduction of molecular oxygen takes place, depending on the experimental conditions. In the absence of suitable ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1021/ic00080a021DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 09:31
Last Modified:13 Mar 2014 13:08
Item ID:13591
Owner Only: item control page

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