Deutsch
Pawlowski, V. and Kunkely, Horst and Vogler, Arnd (1994) Electronic Spectra and Photochemistry of Trichlorostannyl Complexes of Rhodium(III) and Platinum(II). Coordination Chemistry Reviews 132, pp. 23-28.
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Abstract
The absorption spectra of [Rh(SnCl3)4Cl2]3− and [Pt(SnCl3)5]3− are characterized by a similar band pattern. It is suggested that the absorption spectra are dominated by bands which are assigned to intraligand transitions. While solid (NBu4)3[Pt(SnCl3)5] shows a low-temperature emission the rhodium complex is not luminescent. Both complex anions are light sensitive in acetonitrile solution. They undergo an efficient photosubstitution of the trichlorostannyl ligand.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Universitätsbibliothek Regensburg | ||||
| Deposited On: | 17 Mar 2010 10:36 | ||||
| Last Modified: | 21 Jul 2011 00:23 | ||||
| Item ID: | 13594 |
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