Pawlowski, V. and Kunkely, Horst and Vogler, Arnd (1994) Electronic Spectra and Photochemistry of Trichlorostannyl Complexes of Rhodium(III) and Platinum(II). Coordination Chemistry Reviews 132, pp. 23-28.
The absorption spectra of [Rh(SnCl3)4Cl2]3− and [Pt(SnCl3)5]3− are characterized by a similar band pattern. It is suggested that the absorption spectra are dominated by bands which are assigned to intraligand transitions. While solid (NBu4)3[Pt(SnCl3)5] shows a low-temperature emission the rhodium complex is not luminescent. Both complex anions are light sensitive in acetonitrile solution. They undergo an efficient photosubstitution of the trichlorostannyl ligand.
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||17 Mar 2010 09:36|
|Last Modified:||13 Mar 2014 13:08|