Kunkely, Horst and Vogler, Arnd (1994) Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]. Journal of the Chemical Society, Chemical Communications , pp. 2671-2672.
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Abstract
The reversible photolysis of aqueous [2O]4– leads to the evolution of oxygen and the formation of [FeII(edta)]2–; it is suggested that the photoreaction is induced by FeIII to FeIII charge-transfer excitation, which yields FeII and FeIVO in the primary photochemical step.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Universitätsbibliothek Regensburg | ||||
| Deposited On: | 17 Mar 2010 10:35 | ||||
| Last Modified: | 21 Jul 2011 00:23 | ||||
| Item ID: | 13596 |
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