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Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]

Kunkely, Horst and Vogler, Arnd (1994) Photochemistry of the Oxo-bridged Diiron(III) Core. Evolution of Oxygen induced by FeIII to FeII Charge-transfer Excitation of μ-Oxobis[(ethylenediaminetetraacetato)ferrate(III)]. Journal of the Chemical Society, Chemical Communications , pp. 2671-2672.

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Abstract

The reversible photolysis of aqueous [{FeIII(edta)}2O]4– leads to the evolution of oxygen and the formation of [FeII(edta)]2–; it is suggested that the photoreaction is induced by FeIII to FeIII charge-transfer excitation, which yields FeII and FeIVO in the primary photochemical step. ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1039/C39940002671DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 09:35
Last Modified:13 Mar 2014 13:08
Item ID:13596
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