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The Complexed Triphosphaallyl Radical, Cation, and Anion Family [Eine Familie mit komplexiertem Triphosphaallyl-Radikal, -Kation und -Anion]

Scheer, Manfred and Kuntz, Christian and Stubenhofer, Markus and Linseis, Michael and Winter, Rainer F. and Sierka, Marek (2009) The Complexed Triphosphaallyl Radical, Cation, and Anion Family [Eine Familie mit komplexiertem Triphosphaallyl-Radikal, -Kation und -Anion]. Angewandte Chemie International Edition 48 (14), pp. 2600-2604.

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Abstract

Radically complex: The photolytic reaction of [Cp*P{W(CO)5}2] (Cp*=C5Me5) with a diphosphene produces, via a radical intermediate, an air-stable complexed triphosphaallyl radical, in which the unpaired electron is evenly distributed over both terminal P atoms. Oxidation of the radical leads to a triphosphaallyl cation, which is only stable at low temperatures in solution, whereas the stable ...

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Item Type:Article
Date:26 February 2009
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200805892DOI
Keywords:allyl ligands; DFT calculationsM; phosphinidines; phosphorus; radicals
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:16
Last Modified:13 Mar 2014 13:30
Item ID:15094
Owner Only: item control page
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