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Coordination Behavior of the 1,2,3-Triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] with Organometallic Moieties

Deng, Shining and Schwarzmaier, Christoph and Zabel, Manfred and Nixon, John F. and Timoshkin, Alexey Y. and Scheer, Manfred (2009) Coordination Behavior of the 1,2,3-Triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] with Organometallic Moieties. Organometallics 28 (4), pp. 1075-1081.

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Abstract

The reaction of the 1,2,3-triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] (1) with the Lewis acidic complex [PtCl2(PEt3)]2 yields the monosubstituted derivative [Cp′′′Fe(η5-P3C2(H)Ph){PtCl2(PEt3)}] (2), in which the Pt moiety is located at the P atom adjacent to the C(H) group of the cyclo-P3C2 ring. Using an excess of the Pt complex no multiple substitution occurs. In contrast, using [W(CO)5] units ...

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Item Type:Article
Date:29 January 2009
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/om801118kDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:17
Last Modified:13 Mar 2014 13:30
Item ID:15096
Owner Only: item control page

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