Coordination Behavior of the 1,2,3-Triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] with Organometallic Moieties

DOI zum Zitieren dieses Dokuments:: 10.5283/epub.15096

Deng, Shining ; Schwarzmaier, Christoph ; Zabel, Manfred ; Nixon, John F. ; Timoshkin, Alexey Y. ; Scheer, Manfred

PDF
(292kB) - Nur für Mitarbeiter des Archivs

Veröffentlichungsdatum dieses Volltextes: 07 Jun 2010 12:17

Alternative Links zum Volltext:DOI

Details

Bibliographische Daten exportieren

Zusammenfassung

The reaction of the 1,2,3-triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] (1) with the Lewis acidic complex [PtCl2(PEt3)]2 yields the monosubstituted derivative [Cp′′′Fe(η5-P3C2(H)Ph){PtCl2(PEt3)}] (2), in which the Pt moiety is located at the P atom adjacent to the C(H) group of the cyclo-P3C2 ring. Using an excess of the Pt complex no multiple substitution occurs. In contrast, using [W(CO)5] units ...