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Unexpected Differences in the Coordination Behaviour of 1,2,4-Triphosphaferrocenes towards Cu Chloride

Deng, Shining and Schwarzmaier, Christoph and Vogel, Ulf and Zabel, Manfred and Nixon, John F. and Scheer, Manfred (2009) Unexpected Differences in the Coordination Behaviour of 1,2,4-Triphosphaferrocenes towards Cu Chloride. European Journal of Inorganic Chemistry 2008 (31), pp. 4870-4874.

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Abstract

The coordination behaviour of 1,2,4-triphosphaferrocenes [FeCpR(5-P3C2tBu2)] [CpR = Cp (1), Cp (2)] towards CuI chloride is significantly influenced by the substitution pattern of the cyclopentadienyl ring attached to iron. The dimeric copper complexes [{FeCp(5:1:1-P3tBu2C2)}{-CuCl(MeCN)}]2 (3) and [{FeCp (5:1:1-P3tBu2C2)}(-CuCl)]2 (4), in which two 1,2,4-triphosphaferrocenes are linked by two ...

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Item Type:Article
Date:25 September 2009
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200800852DOI
Keywords:Supramolecular chemistry; Copper; Fragmentation reactions; Tri­phosphaferrocenes; Tetraphosphabutadiene ligand
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:19
Last Modified:13 Mar 2014 13:30
Item ID:15101
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