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Reactivity of Transition Metal-Phosphorus Triple Bonds towards Triply Bonded [{CpMo(CO)2}2]: Formation of Heteronuclear Cluster Compounds

Scheer, Manfred and Himmel, Daniel and Kuntz, Christian and Zhan, Shuzhong and Leiner, Eva (2008) Reactivity of Transition Metal-Phosphorus Triple Bonds towards Triply Bonded [{CpMo(CO)2}2]: Formation of Heteronuclear Cluster Compounds. Chemistry - A European Journal 14 (29), pp. 9020-9029.

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Abstract

Thermolysis of [Cp*P{W(CO)5}2] (1) in the presence of [{CpMo(CO)2}2] leads to the novel complexes [{(CO)2Cp*W}{CpMo(CO)2}(,2:1:1-P2{W(CO)5}2)] (6; Cp=5-C5H5, Cp*=5-C5Me5), [{(-O)(CpMoWCp*)W(CO)4}{3-PW(CO)5}2] (7), [{CpMo(CO)2}2{Cp*W(CO)2}{3-PW(CO)5}] (8) and [{CpMo(CO)2}2{Cp*W(CO)2}(3-P)] (9). The structural framework of the main products 8 and 9 can be described as a tetrahedral Mo2WP unit that ...

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Item Type:Article
Date:11 August 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200800804DOI
Keywords:cluster compounds; molybdenum; phosphorus; reactive intermediates; tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:21
Last Modified:13 Mar 2014 13:30
Item ID:15103
Owner Only: item control page
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