Chisholm, Malcolm H. and Dann, Angela S. and Dielmann, Fabian and Gallucci, Judith C. and Wolmershäuser, Gotthelf and Patmore, Nathan J. and Ramnauth, Ramkrishna and Scheer, Manfred (2008) Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4′-Bipyridine with Ambivalent Properties. Inorganic Chemistry 47 (20), pp. 9248-9255.
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The reaction between Mo2(TiPB)4 and 4-iso-nicotinic acid (2 equiv) in ethanol leads to the formation of trans-Mo2(TiPB)2(nic)2, I, where TiPB = 2,4,6-triisopropylbenzoate and nic = 4-isonicotinate. The molecular structures of I and I·2DMSO were determined in the solid state by a single-crystal X-ray study, and its electronic structure was determined by DFT calculations on a model compound, where ...
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|Date:||26 September 2008|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||07 Jun 2010 12:22|
|Last Modified:||13 Mar 2014 13:30|