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Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies

Zheng, Bo and Dong, Hao and Bai, Junfeng and Li, Yizhi and Li, Shuhua and Scheer, Manfred (2008) Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies. Journal of the American Chemical Society 132 (25), pp. 7778-7779.

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Abstract

By fine-tuning the reaction temperature to 5, 15, 30, and 50 °C, respectively, four different complexes, [Cd(HC4O4)2(H2O)4] (1), [Cd4(C4O4)4(H2O)16]•(H2O)2 (2), [Cd(C4O4)(H2O)2] (3), and [Cd(C4O4)(H2O)2] (4), were formed successfully from the identical initial reaction mixture. Moreover, an unprecedented reversible interconversion among the four complexes at the corresponding reaction ...

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Item Type:Article
Date:30 May 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/ja800439pDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:23
Last Modified:13 Mar 2014 13:30
Item ID:15106
Owner Only: item control page

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