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Synthesis and Crystal Structures of Novel Copper(I) Complexes of a Phosphanylborane

Schwan, Karl-Christian and Adolf, Ariane and Bodensteiner, Michael and Zabel, Manfred and Scheer, Manfred (2008) Synthesis and Crystal Structures of Novel Copper(I) Complexes of a Phosphanylborane. Zeitschrift für anorganische und allgemeine Chemie 634 (8), pp. 1383-1387.

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Abstract

The novel copper iodide clusters [Cu3(-I)(3-I)2(PH2BH2·NMe3)3] (2) and [Cu4(-I)2(3-I)2(PH2BH2·NMe3)3] (3) were synthesized by treating CuI with the primary phosphine (H2PBH2·NMe3). The novel features of both compounds, which have been characterized by X-ray crystallography, are the unsymmetrical constitution of the copper iodide core due to the influence of the monodentate phosphorus ligand. This ...

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Item Type:Article
Date:26 May 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/zaac.200800079DOI
Keywords:Boron; Phosphorus; Copper; Iodide; Cluster compounds
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:27
Last Modified:13 Mar 2014 13:31
Item ID:15111
Owner Only: item control page

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