Welsch, Stefan and Gregoriades, Laurence John and Sierka, Marek and Zabel, Manfred and Virovets, Alexander and Scheer, Manfred (2007) Unusual Coordination Behaviour of Pn-Ligand Complexes with Tl+ [Ungewöhnliches Koordinationsverhalten von Pn-Ligandkomplexen gegenüber Tl+]. Angewandte Chemie International Edition 46 (48), pp. 9323-9326.
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Abstract
Pentaphosphaferrocene coordinates as a ligand to the large monocation Tl+. In addition, one of the phosphorus atoms of each cyclo-P5 moiety coordinates to a neighboring Tl+ ion to give a one-dimensional polymer. Even at low temperatures, fast rotation of the P5 rings is observed in solution and in the solid state.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
| ||||
| Keywords: | pi interactions; coordination polymers; phosphorus; thallium; weakly coordinating anions | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Owner: | Martin Kaiser | ||||
| Deposited On: | 07 Jun 2010 14:32 | ||||
| Last Modified: | 21 Jul 2011 00:29 | ||||
| Item ID: | 15132 |
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