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The Unexpected Versatility of P4S3 as a Building Block in Polymeric Copper Halide Networks: 2,3-P, 1,2,3-P and all-P Coordination

Biegerl, Andreas and Brunner, Eike and Gröger, Christian and Scheer, Manfred and Wachter, Joachim and Zabel, Manfred (2007) The Unexpected Versatility of P4S3 as a Building Block in Polymeric Copper Halide Networks: 2,3-P, 1,2,3-P and all-P Coordination. Chemistry - A European Journal 13 (33), pp. 9270-9276.

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Abstract

Layering solutions of P4S3 in CH2Cl2 with solutions of CuCl or CuI in CH3CN gives the coordination polymers (P4S3)3(CuCl)7 (1), (P4S3)2(CuCl)3 (2), (P4S3)(CuI) (3) and (P4S3)(CuI)3 (4), respectively, after slow diffusion. The yellow compounds were characterised by elemental analysis, 31P magic-angle spinning (MAS) NMR spectroscopy and single-crystal X-ray crystallography. The solid-state ...

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Item Type:Article
Date:20 August 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200700761DOI
Keywords:copper halides; NMR spectroscopy; phosphorus; polymers; sulfur
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:34
Last Modified:13 Mar 2014 13:31
Item ID:15135
Owner Only: item control page

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