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An Unusual Building Block for Supramolecular Aggregates: The Mixed Group 15/16 Element Ligand Complex [(Cp*Mo)2(,3-P3)(,2-PS)] [Ein ungewöhnlicher Baustein für supramolekulare Aggregate aus Elementen der Gruppe 15 und 16: der gemischte Ligandkomplex [(Cp*Mo)2(,3-P3)(,2-PS)]]

Gregoriades, Laurence John and Balázs, Gábor and Brunner, Eike and Gröger, Christian and Wachter, Joachim and Zabel, Manfred and Scheer, Manfred (2007) An Unusual Building Block for Supramolecular Aggregates: The Mixed Group 15/16 Element Ligand Complex [(Cp*Mo)2(,3-P3)(,2-PS)] [Ein ungewöhnlicher Baustein für supramolekulare Aggregate aus Elementen der Gruppe 15 und 16: der gemischte Ligandkomplex [(Cp*Mo)2(,3-P3)(,2-PS)]]. Angewandte Chemie International Edition 46 (31), pp. 5966-5970.

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Abstract

Unusual suspect: The complex [(Cp*Mo)2(,3-P3)(,2-PS)] reacts with CuI and Ag[Al{OC(CF3)3}4] to form two novel linear polymers (see structure of CuI derivative; Cu light blue, I violet, Mo blue, P pink, S yellow). Even with X-ray crystallographic data available, the fact that the sulfur atoms in these polymers do not coordinate to the Group 11 metal centers could only be established with the help ...

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Item Type:Article
Date:2 July 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200701343DOI
Keywords:Group 11 metals; molybdenum; phosphorus; sulfur; supramolecular chemistry
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:36
Last Modified:13 Mar 2014 13:31
Item ID:15138
Owner Only: item control page

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