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Conformational Analysis of One-Dimensional Coordination Polymers Based on [Cp2Cr2(CO)4(,2-P2)] by Solid-State Multinuclear NMR Spectroscopy and Density Functional Calculations

Scheer, Manfred and Gregoriades, Laurence John and Zabel, Manfred and Sierka, Marek and Zhang, Long and Eckert, Hellmut (2007) Conformational Analysis of One-Dimensional Coordination Polymers Based on [Cp2Cr2(CO)4(,2-P2)] by Solid-State Multinuclear NMR Spectroscopy and Density Functional Calculations. European Journal of Inorganic Chemistry 2007 (18), pp. 2775-2782.

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Abstract

Reaction of the complex [Cp2Cr2(CO)4(,2-P2)] (2) with copper(I) halides leads to the quantitative formation of the new one-dimensional (1D) linear polymers [CuX{Cp2Cr2(CO)4(,2:1:1-P2)}]n [X = Cl (3), Br (4), I (5)]. Polymers 3-5 are the first examples of supramolecular aggregates incorporating 2 as a connecting moiety. The solid-state structures of 3-5 are compared and their remarkable ...

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Item Type:Article
Date:8 May 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200700092DOI
Keywords:Chromium; Copper; Halides; Density functional calculations; NMR spectroscopy; Phosphorus
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:38
Last Modified:13 Mar 2014 13:32
Item ID:15141
Owner Only: item control page

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