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The Potential of a cyclo-As3-Ligand Complex in Supramolecular Chemistry

Gregoriades, Laurence John and Krauss, Hannes and Wachter, Joachim and Virovets, Alexander V. and Scheer, Manfred and Sierka, Marek (2006) The Potential of a cyclo-As3-Ligand Complex in Supramolecular Chemistry. Angewandte Chemie International Edition 45 (25), pp. 4189-4192.

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Abstract

As3 makes the connection: [Cp*Mo(CO)2(3-As3)] reacts with Ag[Al{OC(CF3)3}4] to yield a novel dimeric complex featuring the cyclo-As3 ligand in an unusual face-bridging coordination mode. Analytical data and DFT calculations support the existence of a monomer-dimer equilibrium in solution (see scheme). [Cp*Mo(CO)2(3-As3)] also reacts with CuX (X=Cl, Br, I) to yield insoluble dimers consisting of ...

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Item Type:Article
Date:24 May 2006
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200600815DOI
Keywords:arsenic; copper; molybdenum; self-assembly; silver
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:58
Last Modified:13 Mar 2014 13:33
Item ID:15186
Owner Only: item control page
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