Vogel, Ulf and Timoshkin, Alexey Y. and Schwan, Karl-Christian and Bodensteiner, Michael and Scheer, Manfred (2006) The formation of Lewis acid/base stabilised phosphanyltrielanes – A theoretical and experimental study. Journal of Organometallic Chemistry 691 (21), pp. 4556-4564.
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Theoretical investigations on the thermochemistry and the reaction mechanism of the formation of Lewis acid/base stabilised phosphanyltrielanes D · H2EPH2 · A (D = Lewis base, A = Lewis acid) were conducted. The reactions of EH3 · D with A · PH3 to form D · H2EPH2 · A and H2 (E = B, Al, Ga; D = NH3; A = BH3, Cr(CO)5) are all exothermic, regardless of whether donors and acceptors are present or ...
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|Date:||15 October 2006|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||DFT calculations; Mechanism; Group 13/15 compounds; X-ray structure analysis|
|Dewey Decimal Classification:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited on:||07 Jun 2010 12:59|
|Last modified:||13 Mar 2014 13:33|