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The formation of Lewis acid/base stabilised phosphanyltrielanes – A theoretical and experimental study

Vogel, Ulf and Timoshkin, Alexey Y. and Schwan, Karl-Christian and Bodensteiner, Michael and Scheer, Manfred (2006) The formation of Lewis acid/base stabilised phosphanyltrielanes – A theoretical and experimental study. Journal of Organometallic Chemistry 691 (21), pp. 4556-4564.

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Abstract

Theoretical investigations on the thermochemistry and the reaction mechanism of the formation of Lewis acid/base stabilised phosphanyltrielanes D · H2EPH2 · A (D = Lewis base, A = Lewis acid) were conducted. The reactions of EH3 · D with A · PH3 to form D · H2EPH2 · A and H2 (E = B, Al, Ga; D = NH3; A = BH3, Cr(CO)5) are all exothermic, regardless of whether donors and acceptors are present or ...

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Item Type:Article
Date:15 October 2006
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1016/j.jorganchem.2006.04.014DOI
Keywords:DFT calculations; Mechanism; Group 13/15 compounds; X-ray structure analysis
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:59
Last Modified:13 Mar 2014 13:33
Item ID:15187
Owner Only: item control page
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