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Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif [Ein sphärischer Cluster aus Vier- und Sechsringeinheiten]

Johnson, Brian P. and Dielmann, Fabian and Balázs, Gábor and Sierka, Marek and Scheer, Manfred (2006) Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif [Ein sphärischer Cluster aus Vier- und Sechsringeinheiten]. Angewandte Chemie International Edition 45 (15), pp. 2473-2475.

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Abstract

Magic ball: A spherical aggregate containing a core of 32 inorganic atoms (see structure) was prepared by coordination of a cyclo-P4 tantalum complex to copper(I) chloride. The phosphorus/copper core exhibits an arrangement of alternating four- and six-membered rings, which are reminiscent of the hypothetical Oh-symmetric fullerene C32.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200503511DOI
Keywords:cluster compounds; density functional calculations; fullerenes; phosphorus; tantalum
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner:Martin Kaiser
Deposited On:07 Jun 2010 15:01
Last Modified:21 Jul 2011 00:29
Item ID:15208
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