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One-Dimensional Polymers Based on [{CpMo(CO)2}2(,2-P2)]: Solid-State Conformation Analysis by NMR Spectroscopy and DFT Calculations

Scheer, Manfred and Gregoriades, Laurence John and Bai, Junfeng and Sierka, Marek and Brunklaus, Gunther and Eckert, Hellmut (2005) One-Dimensional Polymers Based on [{CpMo(CO)2}2(,2-P2)]: Solid-State Conformation Analysis by NMR Spectroscopy and DFT Calculations. Chemistry - A European Journal 11 (7), pp. 2163-2169.

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Abstract

Reaction of the complex [{CpMo(CO)2}2(,2-P2)] (1) with CuI halides leads to the quantitative formation of the novel one-dimensional linear polymers [CuX{Cp2Mo2(CO)4(,2:1:1-P2)}] (X=Cl (4), Br (5), I (6)). The same products 4 and 5 were obtained when 1 was treated with CuCl2 and CuBr2, respectively. The solid-state structures are compared and their remarkable influence on the respective 31P magic ...

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Item Type:Article
Date:15 February 2005
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200401117DOI
Keywords:density functional calculations; molybdenum; NMR spectroscopy; phosphorus; polymers; solid-state structures
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:06
Last Modified:13 Mar 2014 13:33
Item ID:15220
Owner Only: item control page
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