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Reactivity of Lewis Acid/Base Stabilized Phosphanyl- and Arsanylboranes towards a Platinum(0) Complex

Vogel, Ulf and Schwan, Karl-Christian and Hoemensch, Petra and Scheer, Manfred (2005) Reactivity of Lewis Acid/Base Stabilized Phosphanyl- and Arsanylboranes towards a Platinum(0) Complex. European Journal of Inorganic Chemistry 2005 (8), pp. 1453-1458.

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Abstract

The Lewis acid/base stabilized phosphanylboranes and -arsanes [(CO)5W(H2EBH2·NMe3)] (1a: E = P; 1b: E = As) have been shown to react with the platinum(0) complex [(Ph3P)2Pt(C2H4)] under oxidative addition of the E-H bond to the platinum center. The complexes cis-[(Ph3P)2Pt(H)(-EHBH2·NMe3)W(CO)5] (2a: E = P; 2b: E = As) are formed. Complex 2a is unstable in solution at room temperature and slowly ...

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Item Type:Article
Date:21 April 2005
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200400845DOI
Keywords:Arsenic; Boron; Phosphorus; Reactivity; Platinum
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:06
Last Modified:13 Mar 2014 13:34
Item ID:15225
Owner Only: item control page

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