Startseite UB

Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides

Scheer, Manfred and Vogel, Ulf and Becker, Uta and Balzàs, Gàbor and Scheer, Petra and Hönle, Wolfgang and Becker, Michael and Jansen, Martin (2004) Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides. European Journal of Inorganic Chemistry 2005 (1), pp. 135-141.

[img]PDF
Download (170kB) - Repository staff only

at publisher (via DOI)


Abstract

The reaction of [{W(CO)5}2PCl] with K[Co(CO)4] yields the novel compounds [{W(CO)4Co2(CO)6}{µ3-PW(CO)5}2] (3) and [{(CO)4WCo3(CO)6}{µ3-PW(CO)5}3] (4) along with known derivatives [Co2(CO)6{,2-PW(CO)5}2] (1) and [Co3(CO)9{3-PW(CO)5}] (2). The complex [{W2(CO)8(-CO)}{,2:1:1-PW(CO)5}2)] (5) was synthesised by treating Na2[W2(CO)10] with PBr3. Reaction of K[Mn(CO)5] with SbCl3 affords [Sb{Mn(CO)5}3] ...

plus


Export bibliographical data



Item Type:Article
Date:18 November 2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200400640DOI
Keywords:Cobalt; Cluster compounds; Phosphorus; Thermochemistry; Tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:08
Last Modified:13 Mar 2014 13:34
Item ID:15226
Owner Only: item control page

Downloads

Downloads per month over past year

  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact