Scheer, Manfred and Vogel, Ulf and Becker, Uta and Balzàs, Gàbor and Scheer, Petra and Hönle, Wolfgang and Becker, Michael and Jansen, Martin (2004) Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides. European Journal of Inorganic Chemistry 2005 (1), pp. 135-141.
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The reaction of [2PCl] with K[Co(CO)4] yields the novel compounds  (3) and  (4) along with known derivatives [Co2(CO)62] (1) and [Co3(CO)9] (2). The complex [2)] (5) was synthesised by treating Na2[W2(CO)10] with PBr3. Reaction of K[Mn(CO)5] with SbCl3 affords [Sb3] (6) in high yields. The spectroscopic and structural characterisation of the novel products is discussed, as well as the thermolytic behaviour of 2, 3 and 6 for the potential formation of novel phases of transition metal pnictides.
|Date:||18 November 2004|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||Cobalt; Cluster compounds; Phosphorus; Thermochemistry; Tungsten|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||14 Jun 2010 12:08|
|Last Modified:||20 Jul 2011 22:29|