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Hydrodimetalation of tert-Butylphosphaethyne by a Diruthenium Complex: Crystal and Molecular Structure of [Ru2(CO)4(μ-PBut2)(μ-Ph2PCH2PPh2){μ-PC(H)But}]

Böttcher, Hans-Christian and Himmel, Daniel and Scheer, Manfred (2004) Hydrodimetalation of tert-Butylphosphaethyne by a Diruthenium Complex: Crystal and Molecular Structure of [Ru2(CO)4(μ-PBut2)(μ-Ph2PCH2PPh2){μ-PC(H)But}]. Organometallics 23 (22), pp. 5314-5316.

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Abstract

The reaction of [Ru2(CO)3(PBun3)(μ-H)(μ-PBut2)(μ-dppm)] (1a) with tert-butylphosphaethyne leads under hydrodimetalation to the novel phosphaethenyl complex [Ru2(CO)4(μ-PBut2)(μ-dppm){μ-PC(H)But}] (2), which has been characterized by spectroscopic methods as well as by X-ray diffraction. Compound 2 represents the first structurally characterized complex with a phosphaalkenyl ligand of the type ...

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Item Type:Article
Date:2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/om049777hDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:08
Last Modified:13 Mar 2014 13:34
Item ID:15227
Owner Only: item control page

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