Böttcher, Hans-Christian and Himmel, Daniel and Scheer, Manfred (2004) Hydrodimetalation of tert-Butylphosphaethyne by a Diruthenium Complex: Crystal and Molecular Structure of [Ru2(CO)4(μ-PBut2)(μ-Ph2PCH2PPh2)]. Organometallics 23 (22), pp. 5314-5316.
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The reaction of [Ru2(CO)3(PBun3)(μ-H)(μ-PBut2)(μ-dppm)] (1a) with tert-butylphosphaethyne leads under hydrodimetalation to the novel phosphaethenyl complex [Ru2(CO)4(μ-PBut2)(μ-dppm)] (2), which has been characterized by spectroscopic methods as well as by X-ray diffraction. Compound 2 represents the first structurally characterized complex with a phosphaalkenyl ligand of the type μ-PC(H)R bridging two metal centers.
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||14 Jun 2010 12:08|
|Last Modified:||20 Jul 2011 22:29|