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Second Molecular Hyperpolarizability of Mixed Transition Metal, Non-Metal Clusters

Mathur, Pradeep and Chatterjee, Saurav and Singh, Bishnu P. and Kundu, Tapan and Trivedi, Rajiv and Umbarkar, Shubhangi B. and Scheer, Manfred (2004) Second Molecular Hyperpolarizability of Mixed Transition Metal, Non-Metal Clusters. Journal of Cluster Science 15 (1), pp. 13-18.

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The real and imaginary parts of third order nonlinear optical susceptibilities (chi (3)) of 10–4M solutions of [{Fe2(CO)6}(mgr 3-Y3P){CpCr(CO)2}] (Y=S (1) or Se (2)) and the well known precursor clusters [Fe3(CO)9(mgr 3-Y)2] (Y=S (3) or Se (4)) in toluene were measured using Z-scan and ARINS techniques respectively. Compounds 1 and 2 possess nearly three times the gamma R values of their ...


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Item type:Article
Date:29 November 2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Non-linear; optical; mixed-metal; iron; chromium; carbonyl
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Deposited on:14 Jun 2010 12:10
Last modified:13 Mar 2014 13:34
Item ID:15229
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